Product ID:COTTOCOTE S
MSDS Date:12/01/1993
FSC:8030
NIIN:00N062171
MSDS Number: BYGMM

MADISON CHEMICAL INDUSTRIES

490 MCGEACHIE DR
MILTON, ONTARIO CANADA
US

Emergency Phone: 613-996-6666

Info Phone: 905-878-8863

Cage: 2N073

MADISON CHEMICAL INDUSTRIES

Cage: 3AF43

POLYMETHYLENEPOLYPHENYL ISOCYANATE; (POLYMERIC

CAS: 9016-87-9

RTECS: TR0350000

Fraction By Weight: 30-60%

OSHA PEL N/K

ACGIH TLV: N/K

BENZENE, ISOCYANATO-; (PHENYL ISOCYANATE (MONOMER))

CAS: 103-71-9

RTECS: DA3675000

Fraction By Weight: TRACE

OSHA PEL N/K

ACGIH TLV: N/K

P-TOLUENE SULFONYL ISOCYANATE; (PARA-TOLUENE SULPHONYL

CAS: 4083-64-1

Fraction By Weight: 0.5-1.5%

OSHA PEL N/K

ACGIH TLV: N/K

(ORAL, RAT) 10 MG/KG

CAS: 64475-85-0

RTECS: PY8240000

Fraction By Weight: 3-7%

OSHA PEL N/K

ACGIH TLV: N/K

2-BUTANONE;(METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA).

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 5-10%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM/300STEL;9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA 313)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 1-5%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM/75 STEL; 9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

(ORAL, RAT) >4000 MG/KG

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 7-13%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL;9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 0-7%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3; 9495

IRON OXIDE RED; (IRON OXIDE)

CAS: 51274-00-1

Fraction By Weight: 0-7%

OSHA PEL N/K

ACGIH TLV: N/K

3)

CAS: 1308-38-9

RTECS: GB6475000

Fraction By Weight: 0-7%

OSHA PEL N/K

ACGIH TLV: 0.5 MG/M3 TWA AS CR

COPPER, (PHTHALOCYAMINATO (2-1)); (CI PIG BLUE). LD50

CAS: 147-14-8

RTECS: GL8510000

Fraction By Weight: 0-2%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY CAUSE TEMPORARY IRRITATION
OF NOSE, THROAT, LUNGS AND EYES. SENSITIZATION: POSSIBLE THROUGH
REPEATED OVER-EXPOSURE. CARCINOGENICITY: MAY CONTAIN CARBON BLACK
WHICH MAY CAUSE CUMULATIVE HEAR T AND LUNG DAMAGE. REPRODUCTIVE
TOXICITY: MAY CONTAIN LESS THAN 10 PPM HEXAVALENT CHROMIUM WHICH IS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:CHROMIUM (III) OXIDE:NTP 7TH ANNUAL
REPORT ON CARCINOGENS, 1994: KNOWN TO BE CARCINOGENIC.
Effects of Overexposure:HLTH HAZ: KNOWN TO CAUSE CANCER OR REPRODUCTIVE
TOXICITY. CHRONIC: NO LONG TERM CHRONIC EFFECTS KNOWN. EXPOSURE
LIMITS: ALTHOUGH NO FREE MDI MONOMER IS PRESENT, THE 0.005 PPM TLV
CEILING FOR THE MONOM ER SHOULD BE OBSERVED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN:WASH THOROUGHLY WITH SOAP AND H*2O. REMOVE CONTAMINATED
CLOTHING. EYES:IMMEDIATELY FLUSH WITH H*2O FOR AT LEAST 15 MINUTES.
INGESTION:IF CONSCIOUS, DO NOT INDUCE VOMITING. GUARD AGAINST
ASPIRATIO N INTO LUNGS. INHALATION:IF NAUSEOUS ORLIGHTHEADED,
REMOVE TO FRESH AIR, GIVE OXYGEN IF BREATHING IS DIFFICULT. IF
BREATHING STOPPED, BEGIN ARTIFICIAL RESPIRATION. IN ALL CASES GET
MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:>32F,>0C
Lower Limits:<2%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:AVOID SPARKS AND OPEN FLAMES. PROVIDE
POSITIVE VENTILATION. DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE
TOXIC. AIR-LESS SPRAY EQUIPMENT SHOULD BE GROUNDED.

Spill Release Procedures:COVER THE SPILL WITH AN ABSORBENT MATERIAL
SUCH AS SAND OR SWEEPING COMPOUND. PUT MATERIAL INTO CLOSABLE
CONTAINERS. FLUSH CONTAMINATED AREAS WITH WATER, AVOID HEAT, SPARKS
AND FLAMES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP MATERIAL AWAY FROM EXTREME HEAT,
SPARKS AND OPEN FLAMES. STORE IN TIGHTLY CLOSED CONTAINERS AND
PROTECT FROM MOISTURE AND FOREIGN MATERIALS.
Other Precautions:IDEAL STORAGE TEMPERATURE 10-27C(50-80F). IF
CONTAINERS ARE BULGING, EXERCISE CAUTION WHEN OPENING.

Respiratory Protection:WHEN SPRAYING IN CONFINED SPACES WITHOUT
POSITIVE VENTILATION TYPE "C" NIOSH/MSHA RESPIRATORS ARE REQUIRED.
OUTDOORS USE ORGANIC VAPOUR MASK IF RESPIRATORY SYMPTOMS OCCUR.
Ventilation:IN CONFINED AREAS, POSITIVE (FORCED AIR) VENT IS REC. IN
OTHER INDOOR APPLICATNS, PASSIVE VENT (OPENING OF DOORS(SUPDAT)
Protective Gloves:SOLVENT RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (SUPDAT)
Other Protective Equipment:EMERG EYE WASH AND DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . DRESS AS WHEN WORKING W/OIL-BASED (SUP
DAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VENT: AND WINDOWS) IS RECOMMENDED. EYE PROT: AND FULL LENGTH FACE
SHIELD . OTHER PROT EQUIP: PAINT. CLOTHING SHOULD COVER ALL
EXPOSED AREAS OF THE BODY.

Spec Gravity:1.1-1.2 @ 20C
Appearance and Odor:SOLVENT ODOR, PIGMENTED LIQUID

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS.
Stability Condition to Avoid:ELEVATED TEMPERATURES, INCOMPATIBLES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
NITROGEN OXIDES, MDI.
Conditions to Avoid Polymerization:POLYMERIZATION MAY OCCUR WITH WATER
OR HIGH TEMPERATURES.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE &
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.